35-Lecture Course: Introduction to Solid State Chemistry (3.091)

September 7, 2010 · 4 comments

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This course introduces the basic principles of chemistry and these principles are applied to engineering systems. Relationships between electronic structure, chemical bonding, and atomic order are discussed, as well as characterization of atomic arrangements in crystalline and amorphous solids: metals, ceramics, semiconductors, and polymers (including proteins). Using examples from real-life industrial practice, like batteries and fuel cells, Professor Donald Sadoway covers organic chemistry, solution chemistry, acid-base equilibria, electrochemistry, biochemistry, chemical kinetics, diffusion, and phase diagrams.

Sadoway is a Professor of Materials Chemistry at MIT. He earned his BA, MA, and PhD from the University of Toronto.

Course Materials

Introduction | MIT 3.091 Introduction to Solid State Chemist (#1)

- Prof. Donald Sadoway introduces MIT 3.091 Introduction to Solid State Chemistry View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 1 | MIT 3.091 Introduction to Solid State Chemistry (#2)

- Vision Statement, Administrative Details Introduction Taxonomy of Chemical Species Origins of Modern Chemistry View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 2 | MIT 3.091 Introduction to Solid State Chemistry (#3)

- Classification Schemes for the Elements Mendeleyev and the Periodic Table Atomic Structure View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 3 | MIT 3.091 Introduction to Solid State Chemistry (#4)

- Rutherford Model of the Atom, Bohr Model of Hydrogen View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 4 | MIT 3.091 Introduction to Solid State Chemistry (#5)

- Atomic Spectra of Hydrogen, Matter/Energy Interactions Involving Atomic Hydrogen View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 5 | MIT 3.091 Introduction to Solid State Chemistry (#6)

- The Shell Model (Bohr-Sommerfeld Model) and Multi-electron Atoms Quantum Numbers: n, l, m, s View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 6 | MIT 3.091 Introduction to Solid State Chemistry (#7)

- De Broglie, Heisenberg, and Schrödinger The Aufbau Principle, Pauli Exclusion Principle, and Hund's Rules Photoelectron Spectroscopy Average Valence Electron Energy View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 7 | MIT 3.091 Introduction to Solid State Chemistry (#8)

- Octet Stability by Electron Transfer: Ionic Bonding Properties of Ionic Compounds: Crystal Lattice Energy Note: Lecture 7 was not recorded in its entirety. Only the second half of the session is available in video. View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 8 | MIT 3.091 Introduction to Solid State Chemistry (#9)

- Born-Haber Cycle Octet Stability by Electron Sharing: Covalent Bonding Lewis Structures Hybridization View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 9 | MIT 3.091 Introduction to Solid State Chemistry (#10)

- Electronegativity, Partial Charge, Polar Bonds and Polar Molecules Ionic Character of Covalent Bonds, Pauling's Calculation of Heteronuclear Bond Energies View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 10 | MIT 3.091 Introduction to Solid State Chemistry (#11)

- LCAO MO, Energy Level Diagrams for H2, He2, Li2 Hybridization, Double Bonds and Triple Bonds, Paramagnetism and Diamagetism View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 11 | MIT 3.091 Introduction to Solid State Chemistry (#12)

- The Shapes of Molecules, Electron Domain Theory, Secondary Bonding View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 12 | MIT 3.091 Introduction to Solid State Chemistry (#13)

- Metallic Bonding, Band Theory of Solids (Heitler and London), Band Gaps in Metals, Semiconductors, and Insulators, Absorption Edge of a Semiconductor View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 13 | MIT 3.091 Introduction to Solid State Chemistry (#14)

- Intrinsic and Extrinsic Semiconductors, Doping, Compound Semiconductors, Molten Semiconductors View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 14 | MIT 3.091 Introduction to Solid State Chemistry (#15)

- Introduction to the Solid State, the 7 Crystal Systems, the 14 Bravais Lattices View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 15 | MIT 3.091 Introduction to Solid State Chemistry (#16)

- Properties of Cubic Crystals: Simple Cubic, Face-centered Cubic, Body-centered Cubic, Diamond Cubic Crystal Coordinate Systems, Miller Indices View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 16 | MIT 3.091 Introduction to Solid State Chemistry (#17)

- Characterization of Atomic Structure: The Generation of X-rays and Moseley's Law View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 17 | MIT 3.091 Introduction to Solid State Chemistry (#18)

- X-ray Spectra, Bragg's Law View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 18 | MIT 3.091 Introduction to Solid State Chemistry (#19)

- X-ray Diffraction of Crystals: Diffractometry, Debye-Scherrer, Laue Crystal Symmetry View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 19 | MIT 3.091 Introduction to Solid State Chemistry (#20)

- Defects in Crystals: Point Defects, Line Defects, Interfacial Defects, Voids View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 20 | MIT 3.091 Introduction to Solid State Chemistry (#21)

- Amorphous Solids, Glass Formation, Inorganic Glasses: Silicates View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 21 | MIT 3.091 Introduction to Solid State Chemistry (#22)

- Engineered Glasses: Network Formers, Network Modifiers, Intermediates Properties of Silicate Glasses Metallic Glass View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 22 | MIT 3.091 Introduction to Solid State Chemistry (#23)

- Chemical Kinetics: The Rate Equation, Order of Reaction, Rate Laws for Zeroth, First, and Second Order Reactions Temperature Dependence of Rate of Reaction View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 23 | MIT 3.091 Introduction to Solid State Chemistry (#24)

- Diffusion: Fick's First Law and Steady-state Diffusion, Dependence of the Diffusion Coefficient on Temperature and on Atomic Arrangement View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 24 | MIT 3.091 Introduction to Solid State Chemistry (#25)

- Fick's Second Law (FSL) and Transient-state Diffusion; Error Function Solutions to FSL View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 25 | MIT 3.091 Introduction to Solid State Chemistry (#26)

- Solutions: Solute, Solvent, Solution, Solubility Rules, Solubility Product View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 26 | MIT 3.091 Introduction to Solid State Chemistry (#27)

- Acids and Bases: Arrhenius, Brønsted-Lowry, and Lewis Definitions, Acid Strength and pH View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 27 | MIT 3.091 Introduction to Solid State Chemistry (#28)

- Organic Chemistry: Basic Concepts, Alkanes, Alkenes, Alkynes, Aromatics, Functional Groups, Alcohols and Ethers, Aldehydes and Ketones, Esters, Amines View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 28 | MIT 3.091 Introduction to Solid State Chemistry (#29)

- Organic Glasses - Polymers: Synthesis by Addition Polymerization and by Condensation Polymerization View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 29 | MIT 3.091 Introduction to Solid State Chemistry (#30)

- Structure-property Relationships in Polymers, Crystalline Polymers View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 30 | MIT 3.091 Introduction to Solid State Chemistry (#31)

- Biochemistry: The Amino Acids, Peptides, and Proteins View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 33 | MIT 3.091 Introduction to Solid State Chemistry (#32)

- Phase Diagrams - Basic Definitions: Phase, Component, Equilibrium; One-component Phase Diagrams Two-component Phase Diagrams: Complete Solid Solubility View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 34 | MIT 3.091 Introduction to Solid State Chemistry (#33)

- Two-component Phase Diagrams: Limited Solid Solubility Lever Rule View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Lec 35 | MIT 3.091 Introduction to Solid State Chemistry (#34)

- Wrap-up: Closing Remarks about the Course Student Course Evaluations View the complete course at: http://ocw.mit.edu/3-091F04 License: Creative Commons BY-NC-SA More information at http://ocw.mit.edu/terms More courses at http://ocw.mit.edu

Instructor: Donald Sadoway
Location: Mass Institute of Technology
Length: Full Course
Subjects: Chemistry, Full Course

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{ 4 comments… read them below or add one }

Bijoy Kant Jha January 30, 2011 at 10:45 am: Simply Excellent! wish I were his student.

Reply
MAMO GEBREZGIABHER July 28, 2011 at 11:26 am: Hello,Donald Sadoway, I AM, INORGANIC M.Sc, student at Haramaya university IN Ethiopia.
I saw all in all these lectures,It is really wonderfull TEACHING STYLE.
If i were your student, i would have been so happy!!!!!

Reply
Patrick December 5, 2011 at 9:21 pm: I wish I was his student so bad… I would go to MIT and major in chemistry just to do it

Reply
Donald Rice March 12, 2012 at 10:45 pm: greatest teacher ive come across and im a chem student when he says its great stuff….pay attentiom

Reply

35-Lecture Course: Introduction to Solid State Chemistry (3.091)

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